NBC Announces HUGE Guest Stars for Jimmy Fallon's First Week

Lorne Michaels, Executive Producer of "Late Night with Jimmy Fallon," along with Producer Michael Shoemaker, have announced that two-time Academy Award-winning actor, director and producer Robert De Niro will guest star on the show's premiere Monday, March 2 on NBC at 12:35 a.m. ET.

Rock and Roll Hall of Fame singer Van Morrison will perform from his critically acclaimed "Astral Weeks," named by Rolling Stone Magazine in 2003 as one of the top 20 albums of all time.

Also slated to appear on the show during it's inaugural week are such stars as Tina Fey, Jon Bon Jovi and Santigold (Tuesday, March 3); Cameron Diaz and Billy Crudup (Wednesday, March 4); Donald Trump, Serena Williams and Ludacris (Thursday, March 5); and Drew Barrymore and Mario Batali (Friday, March 6).